Browsing by Subject "Biomethane"
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Publication Biomethane production in an innovative two-phase pressurized anaerobic digestion system(2015) Chen, Yuling; Jungbluth, ThomasGeneration of biogas from biomass through anaerobic digestion is receiving increasing attention. Over the past decade, the biogas industry has been developing rapidly in Germany, as well as the rest of the world. In Germany, biogas is generally used in a heat and power plant (CHP) for electricity and heat production. However, most biogas plants are located in a rural area, where heating demands are quite low. Except for biogas plant thermal control, a huge amount of cogenerated heat is often wasted. In order to increase the overall energy utilization efficiency, biogas can be alternatively converted to biomethane of natural gas quality and injected into existing gas grids. By making use of the mature gas transportation and storage systems, biogas production and end utilization can be temporally and spatially separated. Therefore, it is regarded as an efficient and flexible solution to energy issues. Nevertheless, in terms of this application, raw biogas requires, above all, gas purification and upgrading. Carbon dioxide content, in particular, must be reduced from 40–50% in the raw biogas to approximately 4% in the purified gas. Conventional technologies are generally expensive in investment and/or operation. Therefore, an economical option is desired. Within this research project, a two-phase pressurized anaerobic digestion system was developed. The innovative concept aimed to reduce the cost involved in biomethane conversion and injection into the natural gas grids by integration of biogas production, purification and compression in one system. It was expected that a great amount of carbon dioxide could be directly removed from the pressurized digester due to its high solubility. In addition, the methane-rich biogas could be produced at an elevated pressure which could meet the injection standard, and therefore could reduce or even avoid the expenses for further compression. In order to gain better understanding of two-phase pressurized anaerobic digestion, three major studies were conducted: - The pressure effects on two-phase anaerobic digestion - Effects of organic loading rate (OLR) on the performance of a pressurized anaerobic filter in two-phase anaerobic digestion - Effects of liquid circulation on two-phase pressurized anaerobic digestion By this means, the system performance could be examined and the technical feasibility and potential of the new concept could be explored. Moreover, an optimization of the process in a two-phase pressurized anaerobic digestion system could be realized. From both economic and ecological perspective, two-phase pressurized anaerobic digestion offers an interesting process option for biomethane production, making a great contribution to sustainable energy supply.Publication Optimization of thermodynamic parameters of the biological hydrogen methanation in a trickle-bed reactor for the conditioning of biogas to biomethane(2023) Holl, Elena; Oskina, Anastasia; Baier, Urs; Lemmer, AndreasThe increased demand for resources and energy that is developing with rising global consumption represents a key challenge for our generation. Biogas production can contribute to sustainable energy production and closing nutrient cycles using organic residues or as part of a utilization cascade in the case of energy crops. Compared to hydrogen (H2), biogas with a high methane (CH4) content can be fed into the gas grid without restrictions. For this purpose, the CH4 content of the biogas must be increased from 52 to 60% after anaerobic digestion to more than 96%. In this study, biological hydrogen methanation (BHM) in trickling-bed reactors (TBR) is used to upgrade biogas. Design of experiments (DoE) is used to determine the optimal process parameters. The performance of the reactors is stable under all given conditions, reaching a “low” gas grid quality of over 90%. The highest CH4 content of 95.626 ± 0.563% is achieved at 55 °C and 4 bar, with a methane formation rate (MFR) of 5.111 ± 0.167 m3/(m3·d). The process performance is highly dependent on the H2:CO2 ratio in the educts, which should be as close as possible to the stochiometric ratio of 4. In conclusion, BHM is a viable approach to upgrade biogas to biomethane quality and can contribute to a sustainable energy grid.Publication Two-stage high pressure anaerobic digestion for biomethane production(2017) Merkle, Wolfgang; Jungbluth, ThomasThe use of natural gas for power and heat generation in the EU has become particularly prominent since the 1990s. As a result, the whole natural gas infrastructure has been continuously expanded and today has a total length of 2.15 million km and a storage capacity of about 108.3 billion m³. The production of biomethane in the EU and its distribution by natural gas network offers an interesting alternative for the reconfiguration of EU’s energy supply system. Up to now, biomethane is obtained by purifying and upgrading raw biogas in a complex process. In this study, a novel two-stage high pressure anaerobic digestion system was developed. This innovative concept aims to integrate biogas production, purification and pressure boosting within one system. The process is based on the enhanced water solubility of carbon dioxide compared to methane. By operating the methane reactor for biogas production at increased pressures, high amounts of dissolved carbon dioxide can be removed with the liquid effluent from the reactor, resulting in a high-calorific biogas. In batch experiments at pressures up to 30 bar, a significant influence of pressure on the pH-value in the reactor was observed, due to the augmented formation of carbon hydroxide. The study on the effect of a rapid pressure increase up to 100 bar showed no inhibition of the microorganisms in the batch-rigs too, although the microorganisms were not adapted to these environmental conditions. Furthermore, a continuously operated methane reactor was run at pressures up to 50 bar for the first time. The experiments showed that a stable anaerobic digestion process could be run at these pressures nearly without any problems and methane contents above 90% could be achieved. The promising results showed that this technology has great potential in producing on-site high calorific gas also in smaller units. In addition, the costs of post-production gas purification can be significantly reduced, due to the fact that the size of a subsequent gas purification unit can be decreased. Furthermore, the produced gas can be injected into the transnational gas grids without post pressurization or can be used in the transportation sector.