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Article
2026
From coffee waste to wastewater treatment: optimization of hydrothermal carbonization and H₃PO₄ activation for Cr(VI) adsorption
From coffee waste to wastewater treatment: optimization of hydrothermal carbonization and H₃PO₄ activation for Cr(VI) adsorption
Abstract (English)
Spent coffee grounds (SCG) are an abundant agro-industrial waste, and their valorization as activated carbon (AC) offers a sustainable approach for wastewater treatment and heavy-metal remediation. However, the high energy demand of SCG activation limits large-scale application. Hydrothermal carbonization (HTC) reduces energy consumption and enhances material properties. This study evaluated the performance of activated carbon (AC) derived from SCG via HTC, followed by H₃PO₄ activation for Cr(VI) removal, and compared it with non-activated carbon obtained by HTC and pyrolysis. The results highlight the effect of chemical activation on enhancing surface area, porosity, and adsorption efficiency. The predicted optimal IN was 1624.7 mg·g⁻¹, closely matching the experimental value of 1640.1 ± 15.5 mg·g⁻¹, achieved at 426 °C, 92 min, and a hydrochar-to-H₃PO₄ ratio of 1:1.6. The optimized AC exhibited a maximum adsorption capacity (Qₑ) of 33 ± 1.1 mg·g⁻¹ and 99.4 ± 0.1 % Cr(VI) removal under pH 2, 25 mg·L⁻¹ initial concentration, and 2 g·L⁻¹ adsorbent dose. In contrast, the non-activated carbon presented a lower iodine number (1411 ± 70 mg·g⁻¹) and inferior adsorption performance, confirming the key role of H₃PO₄ activation in improving surface reactivity and adsorption sites. Chemical activation proved essential for improving Cr(VI) adsorption, with the H₃PO₄-AC exhibiting the highest capacity. These results demonstrate the potential of SCG-derived AC as a low-cost adsorbent for heavy-metal-rich industrial effluents, supporting circular economy strategies.
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Journal of hazardous materials advances, 21 (2026), 100966.
https://doi.org/10.1016/j.hazadv.2025.100966.
ISSN: 2772-4166
Amsterdam : Elsevier
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Piccoli Miranda de Freitas, C., De Freitas Batista, G., Dalmolin da Silva, M., Checa Gomez, M., Arauzo, P. J., França da Cunha, F., & Kruse, A. (2026). From coffee waste to wastewater treatment: optimization of hydrothermal carbonization and H₃PO₄ activation for Cr(VI) adsorption. Journal of hazardous materials advances, 21. https://doi.org/10.1016/j.hazadv.2025.100966
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English
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620 Engineering
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Sustainable Development Goals
